金属构件重防腐涂料的选择及涂装工艺

分别介绍了用于重防腐涂料底漆的型号为D ICEP(A)和D ICEP(B)的重防腐涂料的基本性质、技术参数和与之配套的4种丙烯酸改性聚氨酯面漆(包括Ⅰ型、Ⅱ型、Ⅲ型和Ⅴ型)的技术参数以及其中甲乙组分的质量比,并介绍了重防腐涂料涂装工艺流程。分别探讨了在底漆和面漆涂装过程中的注意事项,并介绍了喷涂设备技术参数和重防腐涂料配套应用实例。     

在二辛基磷酸钠的微乳液中金属盐的最大含量

测算了二(2-乙基己基)磷酸钠(NaDEHP)或二(正辛基)磷酸钠(NaDOP)、正辛醇，正辛烷、水和金属盐(CoSO4、NiSO4、FeCl2、CuCl2和CaCl2等)组成的均匀单相微乳液中金属盐水溶液的极限增溶量(Vlim)和金属盐的最大含量(Smax)。相同条件下，NaDOP体系中的Vlim和Smax都比NaDEHP体系巾的高得多，这是因为NaDOP中的正辛基的空间位阻小。     

过渡金属硫化物在高级氧化法中的研究进展

近年来,高级氧化技术(Advanced oxidation processes,AOPs)被广泛用于去除废水中的污染物,但高成本、高能耗限制了该技术的应用,开发低成本、高效、可重复利用的催化剂来降低该技术的使用成本是提高AOPs应用的有效手段。过渡金属硫化物(Transition metal sulfides,TMS)具有良好的导电性、机械稳定性和热稳定性,具有带隙可调特性的TMS可用作光催化剂。综述了TMS在AOPs中的应用,TMS可通过不饱和硫暴露金属活性位点提高Fenton法中Fe~(3+)还原为Fe~(2+)的速率,还可直接活化过硫酸盐或作光催化剂。同时介绍了TMS的改性方法,主要通过元素掺杂改性来增加活性位点,降低带隙宽度;通过TMS与金属化合物复合来提高电导率,增强催化活性;通过TMS与碳基材料复合原位生成H_2O_2,降低光生电子-空穴对的重组速率。最后,对TMS在AOPs中的发展方向进行了展望。     

金属氧化物对金属光泽釉呈色的影响

本文采用佛山地区通用原料，通过正交实验，得出了金属光泽釉的最佳组成。实验发现MnO2是发色主要氧化物；使色差减小的氧化物可同时增加光泽度。与以前金属釉配方相比，所需铅的含量大为降低。     

Influences of metallic polymeric materials on the properties of fresh polyester and acrylic polymer concrete

To investigate the influences of three metallic polymeric materials in polyester and acrylic fresh polymer concretes (PCs), PC‐incorporated different levels of these materials have been investigated for their properties of fresh PC. The mix design was made and optimized for workability, strength, and economy, depending on the resin viscosity, the intended use, and the additional quantities of these polymeric materials. The properties investigated include workability, working time, and curing time of fresh PC. It is concluded that these polymeric materials offer the possibility of improving properties of polyester and acrylic fresh polymer concretes. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci, 2006     

稀土产业与化学品综述(下)

介绍国内外稀土工业概况以及国内稀土化工产品生产现状，陈述了稀土化工催化材料发展与进展。     

复合泡沫塑料的性能改进研究

为改善复合泡沫塑料的介电性能,采用金属氧化物粒子填充改性双马来酰亚胺空芯玻璃微球复合泡沫塑料得到了高介电常数、低介质损耗因数、低密度、力学性能良好的电介质材料。     

PET金银镀铝膜专用烘烤漆的配方设计

从金银线专用烘漆的工艺和性能要求出发,探讨了聚酯真空镀铝膜(VMPET)烘漆的配方设计的要素,实验优选出氨基烘漆体系,研究表明氨基树脂和成膜树脂是获得高性能烘漆的重要因素,通过优选氨基烘漆配方各组分,可获得具有较高应用性能的金银线专用烘漆。     

Corrosion-resistant lightweight metallic bipolar plates for PEM fuel cells

Corrosion resistant treated metal bipolar plates with higher rigidity and electrical conductivity than graphite were developed and tested for PEM fuel cell applications. Six replicas of single cells were used three of which were made of graphite composites bipolar plates and the other three of the treated metallic plates. A Membrane Electrode Assembly (MEA) with 5.55 cm² active electrode areas, 0.3 mg cm^–2 Pt loading and Nafion membrane 115 was fitted to each cell and operated under identical conditions. The experimental testing was conducted at room temperature (20 °C). The average value of the data obtained for the three graphite cells was plotted. Similarly, the average value of the data obtained for the three treated metal cells was plotted on the same graph for comparison. Generally, the treated metal bipolar plate provided at least 12% saving in hydrogen consumption in comparison to graphite. This is attributed to the lower bulk and surface contact resistance of the metal used in this study in relation to graphite. The results of lifetime testing, conducted at room temperature under variable loading showed no indication of power degradation due to metal corrosion for at least 1500 hours.     

求解缓变波导中反问题的一种步进方法

对于声学和电磁学中的大尺度反问题,基于直接方法(例如有限元或者无网格方法)的数值计算往往会导致一个巨大的线性系统,因而在计算速度和存储上并不现实.基于求解Helmholtz方程正问题的Dirichlet-to-Neuman(DtN)算子步进方法,提出了一种用于求解波在大尺度缓变波导中传播的反问题的反向基本解算子步进方法(IFOMM).